per atom enthalpy for heat/flux


Thanks Tim for your reply.
I send one pdf. I want to understand wich enthalpy is correct to use it.
thanks.
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enthalpy.pdf (86 KB)

The heat flux from Eapen’s PRL Eq. 3 is derived from fluctuations of energy around the mean (“excess energy”), so to me it makes sense to use this approach for G-K analysis and compute the partial enthalpy for each component. The Eapen and Sarkar papers are both using this definition… I’m not familiar with
Hoheisel’s approach of enthalpy sharing between components.

Tim